I saw that air on the Outdoor Channel a year ago or more I think. They have shooting shows on Wednesdays that air over and over, and Impossible Shots is the best one by far out of several. The famous, charismatic exhibition shotgunner that just died... His name slips my mind at the moment, but he was GREAT, he was a regular on the show. So is Miculek and Mossberg's shotgunner, who is younger but AWESOME using a basic Wal-Mart shotgun. Guys putting out candles with muzzleloaders, 11yo. shooting cards in half with an M4, so on and so on.
That whole show is awesome and HIGHLY recommended. It's THE BEST shooting show on TV, period.