I might be over stepping but it sounds like a brass problem to me. if i am then please disregard.
if not then this is what i do that works.
take a round that you know is having issues chambering, color the entire case with a black marker (dont half ass this, color the entire case so any mark is from the chamber), put it in the chamber and put a little bit of pressure on it to close. dont gorilla hand it but make sure its enough to leave a minor mark on it. pull out the brass and see where it scratched. this will tell you what you need to know.
- mark on the bottom of the brass means that you need to run these through a small base die to size the brass down to the min of saami specs.(i do this with once fired LC due to the machine guns)
- mark on the shoulder means that you need to bump the should back further than you are right now.
- mark on the neck means your neck thickness is too much and may cause you to neck turn your brass.
- if the round is loaded and causing this, check the bullet when you pull it out, if it is too long then there will be a ring around the ogive and that leads to two potential issues there.
- bullet is seated too long and is jamming into the lands.
- if it is factory ammo then your chamber might not be throat-ed properly. i just had to send my match barrel off since this was my issue on a new build.
I would check the brass first as it is the easiest thing to fix.